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As we know your total t/free t levels are in a healthy range so testosterone levels is not your issue regarding achieving a pump in the gym.

You need to look at other factors as I stated diet/training.....................highly doubt at your age you have issues with healthy nitric oxide levels.

Try increasing complex carbs/higher rep ranges/shorter rest intervals between sets/super sets (exercises)/increase your consumption of foods high in NITRATES such as Arugula,kale,spinach,beets,dark leafy greens,radishes,carrots...........................maybe add an l-citrulline supplement.